Synthetic Coordination and Organometallic Chemistry

Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.